茶多酚/还原石墨烯纳米复合物增强羧甲基壳聚糖薄膜性能的研究

Research on the enhancement of carboxymethyl chitosan film with tea polyphenol/reduced graphene nanocomposites

中文关键词:  茶多酚  还原氧化石墨烯  增强剂  羧甲基壳聚糖  复合薄膜

英文关键词:tea polyphenol  reduced graphene oxide  reinforcer  carboxymethyl chitosan  composite film

中文摘要:

      目的 探究茶多酚还原氧化石墨烯(graphene oxide, GO)的能力, 进一步利用茶多酚/还原氧化石墨烯(reduced graphene oxide, RGO)改善羧甲基壳聚糖薄膜的综合性能。方法 首先利用茶多酚的还原性制备出茶多酚/RGO, 通过X射线衍射仪(X-ray diffractometry, XRD)和傅里叶变换红外光谱仪(Fourier transform infrared spectrometer, FT-IR)表征验证。进一步以羧甲基壳聚糖为基材, 甘油为塑化剂, 通过流延法制备出一系列不同茶多酚/RGO含量的复合薄膜, 测试其力学性能、阻隔性能、光学性能及热稳定性等, 分析不同配比对复合薄膜性能的影响。结果 茶多酚和GO的质量比为2:1时, GO被还原的效果较好; 与纯羧甲基壳聚糖膜相比, 当茶多酚/RGO含量为2.0%时, 复合膜的拉伸强度提高了96.9%; 当茶多酚/RGO含量为1.0%时, 水蒸气透过率最低, 为7.0×10?13 [g·cm/(cm2·s·Pa)]; 随着茶多酚/RGO的添加, 复合薄膜能够阻挡50%以上的310 nm以下的紫外光透过, 表现出具有良好的抗紫外性。结论 茶多酚/石墨烯纳米复合物作为增强剂, 可以有效地改善羧甲基壳聚糖薄膜的综合性能, 为进一步拓展其在食品包装领域的应用提供了新的思路。

英文摘要:

      Objective To explore the reducibility of tea polyphenol to graphene oxide (GO), and further improve the properties of carboxymethyl chitosan composite films by tea polyphenol/reduced graphene oxide (RGO). Methods Firstly, tea polyphenol/RGO was prepared with the reducibility of tea polyphenol. The nanocomposite was characterized by X-ray diffractometry (XRD) and Fourier transform infrared spectrometer (FT-IR). Further, with the carboxymethyl chitosan as base material and the glycerol as plasticizer, a series of carboxymethyl chitosan composite films were prepared by tape casting method with different content of tea polyphenol/RGO. The mechanical properties, barrier properties, optical properties and thermal stability were tested, the effects of different content of tea polyphenol/RGO on the properties of the composite films were analyzed. Results The reduction effect of GO was better, as the ratio of tea polyphenol to GO was 2:1. Compared with pure carboxymethyl chitosan film, the tensile strength of the composite film increased by 96.9% with 2.0% content of tea polyphenol/RGO. When the content of tea polyphenol/RGO was 1.0%, the water vapor transmittance was the lowest, which was 7.0×10?13 [g·cm/(cm2·s·Pa)]. With the addition of tea polyphenol/RGO, more than 50% ultraviolet light below 310 nm was blocked by the composite film, which showed good ultraviolet resistance. Conclusion Tea polyphenol/graphene nanocomposites can be used as the reinforcer to effectively improve the comprehensive properties of carboxymethyl chitosan films, which provides a new idea for further development for further expanding its application in the field of food packaging.