食品中氟虫腈的危害及检测方法研究进展

Research progress on the harm of fipronil residue in food and its detection technology

中文关键词:  氟虫腈  应用  毒性  食品  定性检测  定量检测

英文关键词:fipronil  application  toxicit  food  qualitative detection  quantitative detection

中文摘要:

      氟虫腈, 又名锐劲特, 是一种具有苯环结构的有机小分子, 由法国罗钠-普朗克公司开发, 获中国专利授权。氟虫腈是一种苯基吡唑类广谱杀虫剂, 在水中溶解性较好。由于生产成本较低、杀菌效率高, 因而被广泛应用于防治蔬菜、水稻、烟草、棉花、蓄牧业、公共卫生、贮存用品及地面建筑中各类别的作物害虫及卫生害虫。作为一类比较创新且性能好的的灭虫农药, 氟虫腈曾在全国范围内乃至国际上被大量利用。欧盟法律规定, 氟虫腈不得用于人类食品产业链的畜禽养殖过程。我国规定2009年10月1日起禁止使用含氟虫腈成分的农药制剂。欧盟委员会于2013年限制了氟虫腈在农作物保护中的使用。食品中氟虫腈的残留可通过食物链进行富集, 对人体有较强的毒性, 长期积累会诱发各种疾病。本文主要对氟虫腈的标准限量、应用、毒性及各种检测方法进行了综述, 并在此基础上进行展望。

英文摘要:

      Fipronil, also known as ruijinte, is a small organic molecule with benzene ring structure. Fipronil was developed by French company ronalt-planck and licensed by Chinese patent. Fipronil is a broad - spectrum insecticide of phenylpyrazole, which has better solubility in water. Because of low production cost and high bactericidal efficiency, it is widely used to control various crop pests and sanitary pests in vegetables, rice, tobacco, cotton, animal husbandry, public health, storage supplies and ground buildings. As an innovative insecticide with good performance, fipronil has been widely used in China and even in the world. European Union law stipulates that fipronil cannot be used in the livestock and poultry breeding process of the human food industry chain. China has banned the use of pesticide preparations containing fluorozoonitrile since October 1, 2009. The European commission restricted the use of fipronil in crop protection in 2013. The residue of fipronil in food can be enriched through the food chain, which has strong toxicity to human body, and long-term accumulation will induce various diseases. In this paper, the standard limit, application, toxicity and various detection methods of fipronil were reviewed, and forecasted the prospect on this foundation.