饮料酒中氨基甲酸乙酯检测方法研究进展

Development of analysis methods of ethyl carbamate in alcoholic beverages

中文关键词:  氨基甲酸乙酯  饮料酒  形成机制  检测方法

英文关键词:ethyl carbamate  alcoholic beverages  formation mechanism  analysis methods

中文摘要:

      氨基甲酸乙酯存在于黄酒、葡萄酒等酒精类饮料中, 对人体具有潜在致癌作用, 已被国际癌症研究机构确定为2A级致癌物。随着我国居民生活水平不断提高, 酒精类饮料的消费量日趋上升, 导致人均氨基甲酸乙酯的暴露量也日益上升, 但是我国目前仍未对饮料酒中氨基甲酸乙酯做出限量标准。自从1985年加拿大报道了酒中有较高的氨基甲酸乙酯含量后其检测方法备受关注, 本文介绍了用于检测饮料酒中氨基甲酸乙酯的常用方法如气相色谱法、气相色谱质谱联用法、高效液相色谱法、薄层色谱法、傅里叶变换近红外光谱法等, 并简述了其特点及应用。以期能为饮料酒中氨基甲酸乙酯检测方法的发展提供参考, 同时, 我国应尽快对饮料酒中氨基甲酸乙酯做出限量标准以保障饮料酒行业快速、健康发展, 保护我国居民健康。

英文摘要:

      Ethyl carbamate exists in alcoholic beverages such as rice wine and wine, and has potential carcinogenic effect on human body. It has been identified as a class 2A carcinogen by the International Agency for Research on Cancer. With the continuous improvement of the living standard of Chinese residents and the increasing consumption of alcoholic beverages, the per capita exposure of ethyl carbamate is also increasing. However, China has not yet made a limited standard for ethyl carbamate in alcoholic beverages. Since 1985, Canada reported that ethyl carbamate content in alcoholic beverages was high, the detection methods of ethyl carbamate have attracted much attention. This paper introduced the common methods for the determination of ethyl carbamate in alcoholic beverages, such as gas chromatography, gas chromatography-mass spectrometry, high performance liquid chromatography, thin layer chromatography, Fourier transform near-infrared spectroscopy, and described their characteristics and applications, so as to provide a reference for the development of determination methods of ethyl carbamate in beverage alcohol, at the same time, our country should make a limit standard for ethyl carbamate in alcoholic beverages as soon as possible to ensure the rapid and healthy development of alcoholic beverages industry and protect the health of our residents.